Internal energy via Helmholtz free energy

Gibbs—Helmholtz relations are a set of equations that relate thermodynamic potentials between each other.

Conditions:

1. The number of particles in the system is held constant.

Links:

1. Wikipedia, see equivalent form of this law in table.

internal_energy

internal_energy of the system.

Symbol:

U

Latex:

\(U\)

Dimension:

energy

temperature

temperature of the system.

Symbol:

T

Latex:

\(T\)

Dimension:

temperature

volume

volume of the system.

Symbol:

V

Latex:

\(V\)

Dimension:

volume

free_energy

helmholtz_free_energy of the system as a function of temperature and volume.

Symbol:

F(T, V)

Latex:

\(F{\left(T,V \right)}\)

Dimension:

energy

law

U = F(T, V) - T * Derivative(F(T, V), T)

Latex:

\[U = F{\left(T,V \right)} - T \frac{\partial}{\partial T} F{\left(T,V \right)}\]