Internal energy via Helmholtz free energy
=========================================

*Gibbs—Helmholtz relations* are a set of equations that relate thermodynamic potentials between each other.

**Conditions:**

#. The number of particles in the system is held constant.

**Links:**

#. `Wikipedia, see equivalent form of this law in table <https://en.wikipedia.org/wiki/Gibbs%E2%80%93Helmholtz_equation>`__.

.. py:currentmodule:: symplyphysics.laws.thermodynamics.internal_energy_via_helmholtz_free_energy

.. py:data:: internal_energy

    :attr:`~symplyphysics.symbols.thermodynamics.internal_energy` of the system.

Symbol:
    :code:`U`

Latex:
    :math:`U`

Dimension:
    :code:`energy`


.. py:data:: temperature

    :attr:`~symplyphysics.symbols.thermodynamics.temperature` of the system.

Symbol:
    :code:`T`

Latex:
    :math:`T`

Dimension:
    :code:`temperature`


.. py:data:: volume

    :attr:`~symplyphysics.symbols.classical_mechanics.volume` of the system.

Symbol:
    :code:`V`

Latex:
    :math:`V`

Dimension:
    :code:`volume`


.. py:data:: free_energy

    :attr:`~symplyphysics.symbols.thermodynamics.helmholtz_free_energy` of the system as a function of temperature and volume.

Symbol:
    :code:`F(T, V)`

Latex:
    :math:`F{\left(T,V \right)}`

Dimension:
    :code:`energy`


.. py:data:: law

    :code:`U = F(T, V) - T * Derivative(F(T, V), T)`


    Latex:
        .. math::
            U = F{\left(T,V \right)} - T \frac{\partial}{\partial T} F{\left(T,V \right)}