Mean free path of particles in gaseous medium

The mean free path of a gas particle, defined as the average distance the particle travels between consecutive interactions with another particles, depends on the thermodynamical parameters of the gas as well as the interaction cross section.

Notation:

  1. \(k_\text{B}\) (k_B) is boltzmann_constant.

Notes:

  1. Assuming the model of spherical gas molecules, \(\sigma = \pi d^2\), where \(\sigma\) is the cross section and \(d\) is the molecule diameter.

Conditions:

  1. The gas is in a state of thermodynamic equilibrium.

Links:

  1. Wikipedia, the fourth formula.

  2. Chemistry LibreTexts, “27.6.4. Mean Free Path”.

mean_free_path

mean_free_path of particle.

Symbol:

lambda

Latex:

\(\lambda\)

Dimension:

length

pressure

pressure of the gas.

Symbol:

p

Latex:

\(p\)

Dimension:

pressure

temperature

temperature of the gas.

Symbol:

T

Latex:

\(T\)

Dimension:

temperature

cross_section

cross_section of the interaction between the particle and the gas.

Symbol:

sigma

Latex:

\(\sigma\)

Dimension:

area

law

lambda = k_B * T / (sqrt(2) * p * sigma)

Latex:
\[\lambda = \frac{k_\text{B} T}{\sqrt{2} p \sigma}\]